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Effective Date: Jan. 2006
Supplier:
1) Product Identification:
| Product name | silica gel |
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Product use |
gas drying |
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Supplier: |
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2) Composition/Information on Ingredients:
| Ingredient | Weight in product | EC Index No | EC EINECS No | Classification |
| Amorphous silica Gel 1327-36-2 | 100% | n.a | 215-475-1 | n.a |
3) Hazards Identification:
|
Most important hazards: Specific hazards: |
Clasification according to the European Directive on
classification of hazardous preparations 1999/45/EC. Spheres: Material is slippery |
4) First Aid Measures:
| General | Do not breathe dust Wash hands before breaks and immediately after handling the product. No hazards which require special first aid measures |
|
Inhalation |
Remove to fresh air. Get medical attention for any breathing difficulty. |
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Ingestion |
Give several glasses of water to dilute, If large amounts were swallowed, get medical advice. |
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Skin Contact |
Wash exposed area with soap and water. Get medical advice if irritation develops |
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Eye Contact |
Immediately flush eyes with plenty of water: If symptoms persist, call a physician. |
5) Fire Fighting Measures:
|
Fire Extinguishing Media |
The product itself does not burn. Standard procedure for chemical fires |
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Explosion |
Not considered to be an explosion hazard |
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Not use |
not applicable |
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Special Information |
Product on the ground may have a slippery effect. |
6) Accidental Release Measures:
|
Methods for cleaning up |
Contain spillage. Scoop up or vacuum into a container for reclamation or disposal. Avoid dusting. |
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Personal precautions |
Avoid dust formation. Use personal protective equipment |
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Environmental Precautions: |
No special environmental precautions required |
7) Handling and Storage:
| General advice |
Keep Containers dry and tightly closed to avoid moisture adsorption and contamination. Keep in a dry, cool place. |
|
Handling and storage |
Product on the ground may have a slippery effect. Avoid contact with skin and eyes |
8) Exposure Controls/Personal Protection
| Engineering measures | Ensure adequate ventilation, especially in confined areas |
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Hygiene measures |
Wash hands before breaksand immediately after handlingthe product |
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Personal Protective Equipment |
Safety glasses with side-shields. Lightweight protective clothing |
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Respiratory Protection |
Dust: Use approved respiratory protection if exposure limits are exceeded or overexposure is likely. (dust filter type P1) |
| Protective glovers |
rubber or plastic glovers |
| Ventilation | Local exhauset ventilation is recommended to control
exposure to within applicable limits. |
| Ingredient | Weight in Product (%) | ACGIH TLV: EU | Occupational Exposure Limits |
| Amorphous Aluminosilica Gel 1327-36-2 |
100 | None Established | 4 mg/m³ (Inhalable fraction, General dust limit) |
9) Physical and Chemical Properties
|
Appearance |
transparent bead |
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Odor |
none |
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Solubility |
Insoluble |
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Boiling Point |
2980°C |
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Melting Point |
>1000°C |
| Bulk density | 400 -900 kg / m³ |
| Vapor density | Not applicable |
| Vapor pressure | Not applicable |
| pH | app.4 |
| Flash point °C | Not applicable |
| autoignition temperature °C | Not applicable |
| Lower Explosive Limit % | Not applicable |
| Upper Explosive Limit % | Not applicable |
10) Stability and Reactivity
|
Stability Data |
Stable up to 823 °C. Above this temperature Amorphous Silica will transform into Crystalline Silica |
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Hazardous Decomposition Products |
Fresh material: none anticipated |
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Polymerization |
Will not occur |
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Incompatibilitiy (Materials to Avoid) |
This material is a desiccant and can absorb water or arganic liquids and vapors with some generation of heat. |
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Polymerisation - Avoid |
None anticipated |
11) Toxicological Information
| Information on Produt: Chronic Toxicity |
Avoid dust formation. Prolonged exposure may cause chronic effects |
| Potential Health Effects: Inhalaton: |
May result in drying of mucous membranes.May cause irritation of the respiratory tract. |
| Ingestion | May cause stomach discomfort |
| Skin Contact | May cause skin irritation. Drying |
| Eye Contact | Causes eye irritation |
| Chronic Health Hazards | Prolonged or repeated exosure to dust may cause pulmonary problems |
| Information on Componenets | Ingredient Weight in Product | Acute Toxicity -Oral | Acute Toxicity-Inhalation | Acute Toxicity -Dermal | Acute Toxicity -Other |
| Amorphous Silica Gel 1327-36-2 |
100 | Not Available | Not Available | Not Available | Not Available |
Carcinogenicity
| Information on Componenets | Ingredient Weight in Product | IARC (See Notes) | ACGIH(See Notes) | EU Carcionogenicity (See Notes) |
| Amorphous Silica Gel 1327-36-2 |
100 | N3 | N | N |
12) Ecological Information
| Information on Product Environmental Fate | No data available to the best of our knowledge |
| Mobility | Not relevant. Insoluble in water |
| Persistence/Degradeablility | No data available to the best of our knowledge |
| Ecotoxicological Information | No data available |
13) Disposal Consideration
| Disposal of Waste Method | In accordance with local and national regulations |
| Contaminated Packaging | Empty contaminated containers/packaging must be handled according to regulations as given for the hazardous properties of the contamination. |
| Other Information | Used product may have different hazards or properties than the original product. This SDS does NOT apply to spent/used product |
14) Transport Information
| ADR/RID Class: |
Not Regulated |
| IMO/IMDG EmS No.: |
Not Regulated |
| ICAO/IATA ICAO Class |
Not Regulated |
15) Regulatory Information:
| Europe: Indication of Danger | Not a Dangerous Preparation under current legislation |
| Category of Danger | None |
| Risk Phrases | Not applicable |
| Safety Phrases | Not applicable |
| Water endangering class | Not water endangering according to VwVwSof 17 May 1999 (German Legislation) |
| Waste disposal number | For fresh product 06 08 99 (European Waste disposal number) |
16) Other Information
| Revision number | |
| Sections Revised in this Version | All Sections: Reissue from a new MSDS authoring system, and safety data sheet re-classified according to the European Directive on classification of hazardous preparations article 14 of Directive 1999/45/EC |
| Prepared By:
|
Christoph Waller Long Life for Art according to the European regulations 1999/45, 2001/60, 2001/58 and 2001/59 which are mandatory per 31. 7. 2002. |